Introduction to OLED technology

Introduction to OLED technology

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Description: General characteristics- Structure: An organic light-emitting diode (OLED) consists of several semiconducting organic layers sandwiched between two electrodes, at least one of them being transparent. Two simplified de vice structures are shown in figure 1: a one-side emitting device (left) and a transparent one which emits light both upwards and downwards (right). The device is fabricated by sequentially depositing organic layers on a conducting substrate followed by another conducting electrode.

A common device structure comprises a glass substrate coated with indium tin oxide (ITO) as transparent anode and a thin, opaque metal fi lm as cathode. The organic stack including the electrodes is usually thinner than 1 μm. Two classes of organic materials are commonly used for organic light-emitting devices: polymeric substances and so-called “small molecule materials” which do not exhibit any orientating property and therefore form amorphous films.

One interesting aspect of organics-based optoelectronics is the possibility to use simple screen printing or wet deposition techniques for cost-effective fabrication of large-area devices. Nowadays, this applies only to polymeric organics, whereas evaporating techniques still have to be applied for small molecules. Hopping transport and recombination When a DC bias is applied to the electrodes, the injected electrons and holes can recombine in the organic layers and emit light of a certain color depending on the properties of the ...Please navigate Paper pages for more details.

 
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Introduction to OLED technology
1. General characteristics
1.1. Structure
An organic light-emitting diode (OLED) consists of several semiconducting organic layers sandwiched
between two electrodes, at least one of them being transparent. Two simplified de vice structures are shown
in figure 1: a one-side emitting device (left) and a transparent one which emits light both upwards and
downwards (right). The device is fabricated by sequentially depositing organic layers on a conducting
substrate followed by another conducting electrode. A common device structure comprises a glass
substrate coated with indium tin oxide (ITO) as transparent anode and a thin, opaque metal fi lm as
cathode.
The organic stack including the electrodes is usually thinner than 1 μm. Two classes of organic materials
are commonly used for organic light-emitting devices: polymeric substances and so-called “small molecule
materials” which do not exhibit any orientating property and therefore form amorphous films. One interesting
aspect of organics-based optoelectronics is the possibility to use simple screen printing or wet deposition
techniques for cost-effective fabrication of large-area devices. Nowadays, this applies only to polymeric
organics, whereas evaporating techniques still have to be applied for small molecules.

Figure 1: Simplified structures of an organic light-emitting device. On the left, a one-side “bottom-emitting”
device. On the right, a device which can emit in both directions and appears transparent when turned off.

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Introduction to OLED technology

1.2. Hopping transport and recombination
When a DC bias is applied to the electrodes, the injected electrons and holes can recombine in the organic
layers and emit light of a certain color depending on the properties of the organic material. Since charge
carrier transport in organic semiconductors relies on individual hopping processes between more or less
isolated molecules or along polymer chains (figure 2), the conductivity of organic semiconductors is several
orders of magnitude lower than that of their inorganic counterparts. Furthermore, the concept of energetic
bands with highly delocalized wave functions is not applicable to organic electronics. Instead of “valence
band” and “conduction band”, the relevant terms are “HOMO level” (highest occupied molecular orbital
level) and “LUMO level” (lowest unoccupied molecular orbital level). Before actually decaying radiatively, an
electron-hole pair will form an exciton in an intermediate step, which will eventually emit light when it
decays. Depending on its chemical structure, a dye molecule can be either a fluorescent or a
phosphorescent emitter. Only in the latter, all excitons – singlets and triplets – are allowed to decay
radiatively. In the former, however, three quarters of all excitons – the triplet excitons – do not emit any
light. Fluorescent emitters therefore have a maximum intrinsic efficiency of only 25 % and their application
is avoided if possible. However, up to now, the lifetimes of phosphorescent emitters, especially at a short
wavelength (blue), are inferior to those of fluorescent ones.

Figure 2: Hopping transport and recombination inside an OLED.

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Introduction to OLED technology

1.3. Emission spectrum
Typical emission spectra of organic molecules are broad (as shown in figure 3). As stated before, the
emission color is a material property. Thus, the total emission can be tuned to virtually any color, including
white at any color temperature, by stacking several different emitting layers in a single device. This is
possible since the organic layers are almost transparent in the visible spectral range. Most white OLEDs
contain a red, a green and a blue emission layer to create high-quality white light.

Figure 3: Typical emission spectra of organic materials. The diagram shows spectra of red, green and blue
emitters and their superposition which yields white emission at a high color rendering index.
1.4. Doping
In organic semiconductor technology, electrical doping is used to increase the conductivity of the material
and to enhance the carrier injection from the electrodes into the organic materials. This allows for the
design of devices with intrinsically undoped active layers embedded in p-type and n-type-doped layers,
which are therefore referred to as “PIN diodes”. In addition to an improved electrical performance, such a
design also provides the opportunity to increase the thickness of the device
while maintaining the operating voltage almost constant. The overall thickness of the device between the
electrodes should amount to some hundred nanometers to provide sufficient protection against electrical
short-circuits. These are often caused by the presence of particles on the substrate during evaporation of
the organic layers or by the roughness of the substrate.

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Introduction to OLED technology

Doping also enables a series connection of several active layers in a higher-stacked structure (figure 4). An
intermediate PN junction operated in reverse direction behaves like a tunnel contact: the carriers can
directly pass from the HOMO level of one layer to the LUMO level of the adjacent layer. In the OLED
community, these junctions are often called “charge generation layers (CGLs)” because electron-hole pairs
are created at the interface and separated by the field. A device structure with immanent series connection
is referred to as “stacking”. A twofold white stacked device, for example, can basically achieve the same
luminance levels as a simple device – at half the current, since there are two emitting units, but at twice the
voltage. Compared with simple PIN devices, stacked device architectures offer several advantages in terms
of lifetime, optical performance etc. These will be discussed later.

Figure 4: Stacked device architecture.

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Introduction to OLED technology

1.5. Encapsulation
The organic layers have to be protected against air as they are sensitive to moisture and oxygen and
decompose when exposed. A possible encapsulation technique is shown in figure 5. A thin but dense
amorphous oxide layer is deposited onto the cathode, which provides a sufficient permeation barrier. Due to
its thinness, this thin-film encapsulation (TFE) has to be protected from mechanical damage, for example
by laminating an additional glass layer onto it, by applying a lacquer coating etc.

Figure 5: Thin-film encapsulation.
1.6. Optical cavity
The thin layer system of an OLED represents an optical cavity in the direction of the surface normal, i.e. an
optical system with a total thickness of some wavelengths of the emitted light and a mirror at each end.
Strictly speaking, the OLED is a half-cavity because only the metal cathode acts as a real mirror.
Depending on its thickness and the refractive indices of the materials therein, the cavity shows one or more
shallow resonances for light at a certain wavelength. For light rays that leave the device at an angle higher
than the normal angle, this resonance condition is shifted to larger wavelengths. Consequently, the
emission color of an OLED may display a pronounced angular dependency which can be minimized b y
clever engineering of the layer thicknesses and the positions of the emitters with respect to the reflecting
cathode. Furthermore, this means that when generating light within a cavity, there is always an optimal
position that provides maximum efficiency for a layer that emits light at a certain wavelength. The optimal
position of an emitter can be achieved by tuning the layer thicknesses of the non-emitting layers.

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Introduction to OLED technology

1.7. Wave-guiding properties
In addition to forming a microcavity, the layer stack also has wave-guiding properties. Light generation in
the active layers occurs isotropically, but only a small part, i.e. light with a direction of propagation within the
escape cone, which is defined by the condition of the total internal refl ection at the in terfaces, is actually
able to leave the device. A large fraction (about 85 %) is wave-guided in the organic layers as well as
the substrate glass and is lost for illumination purposes. One way to overcome this limitation is to add an
index-matched layer containing scattering particles to the substrate glass, i.e. a diffuser film. Light traveling
in the substrate will enter the diffuser film, alter its direction when hitting a particle and eventually leave the
diffuser film at a higher angle. The benefit is a higher extraction efficiency and therefore a higher overall
device performance and good color mixing due to statistical scattering of all wavelengths, which results in a
much lower angular dependency of the emission color. The only drawback of applying a diffuser film is the
loss of the mirror-like appearance when the device is turned off, even if the diffuser film itself has a highgloss surface.
1.8. Conductivity
A major challange of large-area OLEDs is the limited conductivity of the electrode material, in particular that
of the transparent conducting oxides (TCOs), e.g. indium tin oxide (ITO), which is about two orders of
magnitude lower than that of aluminium, for example. This leads to a significant voltage drop across the
transparent electrode and causes variations in the local driving voltage of the active layers depending on
the distance to the electrical contacts. Consequently, the emission intensity decreases from the periphery of
the device towards its center. In order to lower the lateral voltage drop, thin metal bus lines can
be deposited on top of the ITO anode, which increases the mean conductivity of the anode, while
shadowing only a minor fraction of the active area and thus yielding a more uniform luminance pattern. The
equivalent circuit of a large-area device is a series connection of three resistors, representing the anode,
the organic layers and the cathode. The higher the differential resistivity of the organic layers at the
operating point, the lower is the voltage drop across the electrodes which results in an enhanced uniformity.
As stacked device architectures have a much higher differential resistivity, stacking is a way to increase the
uniformity and output of large-area devices without having to apply bus lines.

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Introduction to OLED technology

1.9. Lifetime
During the lifetime of an OLED, the luminance will decrease monotonically at constant current. The
resistivity and thus the operating voltage will increase accordingly. The lifetime scales super-linearly with
both the emitted radiation intensity (or current density) and the temperature. The temperature,
in particular, has to be considered when designing OLED based luminaires. At high luminance levels, largearea devices may have considerably elevated temperatures during operation and the possibility of heat
exchange with the surroundings should be provided in order to ensure a long lifetime of the device. In this
case, stacked device architectures once again offer the possibility to lower the individual emission of
each unit, thus slowing down their aging mechanisms, while keeping the overall emission constant.
1.10. Special Features
OLEDs offer several unique features:
 They can be very thin, mainly limited by the thickness of the substrate and encapsulation, and therefore
very lightweight.
 They are glare-free area light sources which can be transparent or have either a mirror -like or milky
appearance when turned off.
 They offer high color quality and turn on instantly when current is applied.
 They have the potential to be equally or more efficient and long-living than fluorescent lamps, while being
100 % mercury-free.
 They emit neither UV nor IR radiation.
 Future products based on OLED technology may even be shapeable or flexible.

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Introduction to OLED technology

2. Electro-optical characteristics
2.1. Emission
In good approximation, OLEDs are Lambertian surface emitters, which means that they have the same
apparent radiance when viewed from any angle. This characteristic can be modified to some extent by
changing the composition of the microcavity. Effective beam shaping is only possible by means of
additional external optical elements such as microlens arrays. As described before, the emission color of an
OLED displays a notable angular dependency which can be minimized by applying a diffuser fi lm on the
emitting surface. As shown in figure 6, the angular shift of the color in CIE space can be reduced by more
than one order of magnitude by means of a diffuser, while enhancing the outcoupling efficiency up to
50 % at the same time.

Figure 6: Color coordinates of the OLED emission at different viewing angles from 0°
to 75° without and with diffuser film on the surface.

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Introduction to OLED technology

2.2. Emission intensity
The emission intensity of an OLED is usually characterized by its luminance, which is a measure of the
luminous intensity per unit area of light traveling in a given direction. The unit for luminance is cd/m², often
also called “nit”. Typical luminance values range from 300 cd/m² for mood lighting up to a few thousand
cd/m² for general illumination. This translates into a luminous flux between 10 and 100 lumen for a device
area of 100 cm². The efficacy of OLEDs and other light sources is measured in lumen per watt and is called
“luminous efficacy”. Sometimes, specifications also include the external quantum efficiency, which relates
the number of generated photons to the number of injected electron-hole pairs.
2.3. I-V und I-L characteristics
Typical relative current-voltage and current-luminance characteristics are shown in figure 7. In good
approximation, the luminance is directly proportional to the operating current. Stacked devices are driven at
a multiple of the operating voltage of a simple device at the same luminance, depending on the number of
emitting units. At the same time, the operating current is lower, so that the luminous efficacy is about the
same for both device architectures. However, the differential resistivity, i.e. the slope of the voltageluminance characteristics, is reduced, which makes stacked architectures favorable for the fabrication of
large-area devices (see section 1.4.).

Figure 7: I-V (left) and I-L (right) characteristics in relative units. A relative current or luminance of 1 and a
voltage of 0 refer to typical operating conditions.

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Introduction to OLED technology

2.4. Color rendering index

07/14 Subject to change without notice. Errors and omission excepted.

The color rendering index (CRI) is a quantitative measure of the ability of a light source to reproduce the
colors of various objects similarly to a natural light source. A CRI of 100 means that the light source has the
same illuminating properties as incandescent light (CCT < 5,000 K) or daylight (CCT > 5,000 K). Any value
below 100 indicates a deficiency in some spectral region. As mentioned in section 1.3., the emission
spectrum of an organic molecule is naturally broad and it is easy to achieve a CRI above 80 by combining a
red, a green and a blue emitter (as shown in figure 3). In addition, when looking at the spectrum, it becomes
apparent that OLEDs emit neither UV nor IR radiation.

OSRAM OLED GmbH
OSRAM OLED GmbH

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93049 Regensburg, Germany
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Phone +49 941 850-0
Phone +49 941 850-0
www.osram-oled.com
Fax
+49 941 850-XXXX
www.osram-oled.com

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